Product ID:UNLEADED 87 - 7.8RVP
MSDS Date:04/30/1992
FSC:9130
NIIN:01-208-4172
MSDS Number: BRFTQ

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 318-491-6215 800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 7X110

CITGO PETROLEUM CORP

3758 TULSA, OK 74102 US

Telephone: 918-495-5933

Cage: 7X110

NAPHTHA (PETROLEUM SPIRITS OR BENZIN)

CAS: 8030-30-6

RTECS: DE3030000

Fraction By Weight: 85-98%

OSHA PEL 100 PPM

ACGIH TLV: 300 PPM

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LOWER ALIPHATIC ALCOHOLS

Fraction By Weight: 0-11%

LOWER ALIPHATIC ETHERS

Fraction By Weight: 0-15%

TERT-BUTYL ALCOHOL (SARA III)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 0-10%

OSHA PEL 100 PPM

ACGIH TLV: 100PPM 9394

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-5%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD HUMAN(150LBS)=0.3-8OZ
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL:VAPORS CAUSE INTOXICATION,LUNG
IRRITATION.SKIN:DEFATTING OF THE SKIN.EYE:IRRITANT.INGEST:GI TRACT
IRRITATION.CAN CAUSE LUNG DAMAGE IF VOMITTED AFTER SWALLOWING.
CHRONIC:BENZENE IS A CARCINOGEN W HICH AFFECTS THE BLOOD FORMING
ORGANS.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of
Overexposure:INHAL:EUPHORIA,EDEMA,HEADACHEMDIZZINESS,DROWSINESS,CON
VULSION,COMA,CYANOSIS,GENERALIZED DEPRESSION.INGEST:BURNING OF THE
MOUTH,VOMITING DIARRHEA.AT ABOUT 1 OZ:GENERAL
DEPRESSION,SEDATION,RESPIRATORY D EPRESSION,COMA.
Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATITIS.

First Aid:IHNAL:REMOVE TO FRESH AIR.GIVE ARTIFICIAL RESPIRATION OR
OXYGEN IF NEEDED.CALL PHYSICIAN.SKIN:REMOVE CONTAMINATED
CLOTHING.WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER.CALL
PHYSICIAN.INGEST:DO NOT I NDUCE VOMITING.IF VOMITING OCCURS,LAY
VICTIM ON LEFT SIDE,HEAD DOWN.GET PROMPT QUALIFIED MEDICAL
ATTENTION.

Flash Point Method:COC
Flash Point:-45F,-43C
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM,WATER FOG.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FLASHBACK HAZARD-VAPORS ARE HEAVIER THAN
AIR AND TRAVEL ALONG THE GROUND;FLOWING GASOLINE GENERATES STATIC
ELECTRICITY.

Spill Release Procedures:REMOVE SOURCES OF IGNITION.VENTILATE AREA.PICK
UP SMALL SPILLS WITH NON-FLAMMABLE ADSORBANT(EG.DIATOMACEOUS
EARTH,CLAY);PLACE IN APPROPRIATE CONTAINER FOR DISPOSAL.CONTAIN
LARGE SPILLS;PLACE A FIRE FI GHTING FOAM BLANKET OVER THE SPILL.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN FLAMMABLE LIQUID AREA.KEEP
CONTAINER TIGHTLY CLOSED.GROUND AND BOND CONTAINERS WHEN
TRANSFERRING LIQUID.
Other Precautions:AVOID CONTACT WITH TH LIQUID;AVOID BREATHING VAPORS.

Respiratory Protection:USE A SELF-CONTAINED BREATHING APPARATUS OR
NIOSH RESPIRATOR IN THE LACK OF ENVIRONMENTAL CONTROLS OR IN
ENCLOSED SPACES(USE ONLY AN SCBA).
Ventilation:ENVIRONMENTAL CONTROLS WHICH MAINTAIN THE EXPOSURE LEVEL
BELOW 300PPM.
Protective Gloves:NITRILE,VITON
Eye Protection:SPLASH RESISTANT TYPE
Other Protective Equipment:CLOTHING TO PROTECT SKIN FROM LIQUID
CONTACT.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NONE

HCC:F1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:95.0F,35.0C
Vapor Pres:510-760
Vapor Density:3-4
Spec Gravity:0.75
Evaporation Rate & Reference:<1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID;LIGHT YELLOW OR CLEAR;GASOLINE ODOR
Percent Volatiles by Volume:HIGH

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,STRONG ACIDS,CAUSTICS.
Stability Condition to Avoid:HIGH HEAT,SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE.

Waste Disposal Methods:THIS ITEM IS CONSIDERED RCRA HAZARDOUS
WASTE(TOXIC AND IGNITABLE).DISPOSE OF IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.